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Hazardous chemicals are substances, mixtures and articles used in the workplace that can be a health or physicochemical hazard if not handled or stored correctly.
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Corrosive Signs are crucial when handling hazardous materials. Alert those in the vicinity of the risks and dangers clearly and effectively.
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To qualify for the small quantity exception the shipper must ensure all conditions below detailing classes, quantities and containers are met.
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The storage of LPG, Class 3 (flammable liquids), Class 6 (toxic substances and Class 8 (Corrosive substances may require a dangerous substances licence.
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The emergency plan must be provided to the emergency services organisation if the quantity of hazardous chemicals stored and used at the workplace exceed manifest quantities. The table below list manifests quantities and shows the link between GHS classes and categories and equivalent classes of dangerous goods under the ADG Code. The person must revise the plan in accordance with any recommendations the primary emergency services organisation provides about its effectiveness.
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PCBUs must manage risks associated with using, handling, generating or storing hazardous chemicals at a workplace. A register of hazardous chemicals at the workplace must be prepared and kept up-to-date. The register must be readily accessible to workers who work with hazardous chemicals and to anyone else likely to be exposed to a hazardous chemical at the workplace.
PCBUs must always aim to eliminate a hazard and associated risk first. If this is not reasonably practicable, the risk must be minimised by using one or more of the following approaches:
A PCBU must ensure that a worker is not exposed to airborne contaminants above the workplace exposure standard. The list of workplace exposure standards for airborne contaminants is contained within the publication Workplace exposure standards for airborne contaminants or these are also available within the Hazardous Chemicals Information System database.
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Physicochemical hazards generally result from the physical or chemical properties, like flammability, corrosiveness, oxidising agents or their explosive potential.
The identity of chemicals in the workplace can usually be determined by looking at the label and the SDS and reading what ingredients are in each chemical or product. Manufacturers and importers are required to provide labels and SDSs, and must review the SDS at least once in every five years.
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A PCBU must prepare an effective emergency plan for the workplace. The purpose of the emergency plan is to plan for, and thus minimise, the effects of any dangerous occurrence or near miss at a workplace resulting from the handling and storage of hazardous chemicals.
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Specific guidance on what a manufacturer or importer must include in an SDS and label can be found in the following Codes:
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Any mix of chemicals from items 11, 29 and 42 where none of the items exceed the quantities in columns 4 or 5 on their own
Health hazards such as skin irritants, carcinogens or respiratory sensitisers can have an adverse effect on a worker's health as a result of direct contact with or exposure to the chemical, usually through inhalation, skin contact or ingestion.
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For the purposes of the below table, if a flammable liquid of category 4 is used, handled or stored in the same spill compound as one or more flammable liquids of categories 1, 2 or 3, the total quantity of flammable liquid is determined as if the flammable liquid of category 4 had the same classification as the flammable liquid in the spill compound with the lowest flash point. For example, 1000L of flammable liquid category 1 and 1000L of flammable liquid category 4 is considered to contain 2000L of flammable liquid category 1.
PCBUs responsible for hazardous chemicals should refer to the Managing risks of hazardous chemicals in the workplace - Code of Practice for further details.