The common metals are not affected by dry ammonia. Moist ammonia will not corrode iron or steel, but will react rapidly with copper, brass, zinc and many alloys, especially those containing copper. Only steel or ductile iron should be used for ammonia containers, valves, fittings and piping.

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Liquid anhydrous ammonia is lighter than water, having a density of 42.57 pounds per cubic foot at -28°F, while as a vapor, ammonia is lighter than air, its relative density is 0.597 compared to air at atmospheric pressure and a temperature of 32°F. Under the latter conditions, one pound of ammonia vapor occupies a volume of 20.78 cubic feet. At 70°F and at atmospheric pressure, one pound of ammonia vapor occupies a volume of 22.5 cubic feet and yields 45 cubic feet of dissociated gas at a ratio of 25% nitrogen and 75% hydrogen.

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Notice: We believe the information contained here to be accurate and reliable; however, Tanner Industries, Inc. assumes no liability or responsibility in connection with the information or suggestions herein contained. Moreover, it should not be assumed that every acceptable test or safety procedure or method, precaution, equipment or device is contained within, or that abnormal or unusual circumstances may not warrant or suggest further requirements or additional procedures.

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Anhydrous ammonia is the compound formed by the combination of the two gaseous elements, nitrogen and hydrogen, in the proportion of one part of nitrogen to three parts of hydrogen by volume. Since one volume of nitrogen weighs fourteen times as much as one volume of hydrogen, on a weight basis, the ratio is fourteen parts of nitrogen to three parts of hydrogen, or about 82% nitrogen and 18% hydrogen.

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The information contained here should not be confused with federal, state, municipal, or insurance requirements, or with national safety or building codes, and no representations or warranties are made with respect thereto.

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Requirements for the Storage & Handling of Anhydrous Ammonia Compressed Gas Association 14501 George Cart Way, Suite 103 Chantilly, VA 20151-2923 www.cganet.com

Under normal conditions, ammonia is a very stable compound. It takes excessive temperatures (about 840° to 930°F) to cause it to dissociate slightly at atmospheric pressure. When this happens, the dissociated products are nitrogen and hydrogen. Ammonia gas burns in a mixture with air within a limited range. The flammable limits at atmospheric pressure are 15% to 28% by volume of ammonia in air. Experiments conducted by Underwriters Laboratories indicate that an ammonia-air mixture in a standard quartz bomb will not ignite at temperatures below 1562°F. When an iron bomb, having a catalytic effect, was used, the ignition temperature dropped to 1204°F.

Molecular symbol: NH3 Molecular weight: 17.032 Boiling point at one atmosphere: -28°F Freezing point at one atmosphere: -108°F Critical temperature: 270.32°F Critical pressure: 1657 psia Vapor density at -28°F and one atmosphere: 0.056697 lb/cubic ft. Heat of Combustion: 8001 (LHV) / 9551 (HHV) Latent heat of Vaporization: 589 Btu/lb

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Mandatory signs specify that an instruction must be carried out. Symbols (or pictograms"") are depicted in white on a blue circular background.

Because of its great affinity for water, care must be taken in the storage and handling of ammonia to keep it dry. "Anhydrous" means "without water." When ammonia gas is dissolved in water, the resulting material is ammonium hydroxide, or "aqua" ammonia. The two materials should not be confused.

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Dissociated ammonia is frequently used as a furnace atmosphere for heat treating metals. Dryness is an important factor. It is difficult to measure the moisture content of the ammonia; however, the moisture content of the dissociated gas can be readily determined by measuring its dewpoint.

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International Institute of Ammonia Refrigeration Phone: 703-312-4200 1110 North Globe Road, Suite 250 Arlington, VA 22201

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At atmospheric temperature and pressures, anhydrous ammonia is a pungent colorless gas. Anhydrous ammonia boils at -28°F and freezes to a white crystalline mass at -108°F. When heated above its critical temperature of 270.3°F, ammonia exists only as a vapor regardless of the pressure. Between the melting and critical points, liquid ammonia exerts a vapor pressure, which increases with rising temperature. When liquid ammonia is in a closed container, it is in equilibrium with ammonia vapor and the pressure within the container bears a definite relationship to the temperature.